Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis
Fecha
2015Autor
Bordón, Alexander Germán
Jorge, María Josefa
Profeta, Mariela Inés
Romero, Jorge Marcelo
Jorge, Nelly Lidia
Castro, Germán Alberto
Metadatos
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The thermal decomposition reaction of Cyclic
GlutaraldehydeDiperoxide (3,6-dibutanal-1,2,4,5-tetroxane) in
solution of methanol in the temperature range of 130.0-166.0°C and
initial concentration of 1.69 x10-3 mol/L, follows first-order kinetic
laws. Under the experimental conditions, the activation parameters of
the reaction are bigger than the obtained ones for other tetroxanos
with different substituent’s in the same solvent, which indicates us
that the substituents stabilize the condition of transition decreasing
the energetic barrier.
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